9780030206931

SpartanModel replaces the plastic models used by past generations of organic chemistry students. This set of easy-to-use digital builders allows you to construct and manipulate 3-D molecules of any size or complexity. Each copy includes software on CD-ROM, an extensive molecular database, 3-D glasses, and a Tutorial and User's Guide with 50 pages of activities for organic chemistry.

Preface

vii

Glossary

xv

Lewis Structures

1

(48)

Molecules and Functional Groups

1

(24)

Saturated Groups

1

(5)

Unsaturated Groups

6

(8)

Larger Molecules

14

(6)

Formal Charge

20

(5)

Ions

25

(11)

Cations

25

(6)

Anions

31

(5)

Free Radicals

36

(3)

Answers

39

(10)

Resonance Structures

49

(39)

Simple Ions

50

(8)

Cations

50

(5)

Anions

55

(3)

Free Radicals

58

(2)

Benzene and Benzenoid Aromatic Compounds

60

(5)

More Complicated Ions

65

(7)

Molecules Having Resonance Structures with Charge Separation

72

(5)

Answers

77

(11)

Mechanisms

88

(74)

Sigma Bond Breaking

88

(4)

Sigma Bond Making

92

(3)

Simultaneous Bond Making and Breaking

95

(25)

Sigma Bond Making and Breaking

95

(7)

Homolytic Sigma Bond Making and Bond Breaking

102

(3)

Sigma Bond Making and Pi Bond Breaking

105

(5)

Pi Bond Making and Sigma Bond Breaking

110

(8)

Homolytic Sigma Bond Making and Pi Bond Breaking

118

(2)

Complex Mechanisms

120

(7)

Rearrangements

127

(8)

Ring Closures

135

(3)

Answers

138

(24)

On Solving Mechanism Problems

162

(20)

Theme I---The Intercepted Intermediate

166

(2)

Theme II---Rearrangement

168

(1)

Theme III---An Unexpected Product

169

(1)

Theme IV---Stereochemistry

170

(5)

Answers

175

(7)

Some Reactions from Biochemistry

182

(16)

Bioorganic Reactions

182

(5)

Enzymes

187

(6)

Coenzymes

193

(5)

Answers

198

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Pushing Electrons: A Guide for Students of Organic Chemistry, 3rd

Pushing Electrons: A Guide for Students of Organic Chemistry, 3rd

0030206936

Summary

Table of Contents

Supplemental Materials