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Power Ultrasound in Electrochemistry From Versatile Laboratory Tool to Engineering Solution

by: Pollet, Bruno

Power Ultrasound in Electrochemistry From Versatile Laboratory Tool to Engineering Solution

by: Pollet, Bruno

ISBN 13:
9780470974247
ISBN 10:
0470974249
Edition: 1st
Format: Hardcover
Copyright: 03/05/2012
Publisher: Wiley

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Summary

The use of power ultrasound to promote industrial electrochemical processes, or sonoelectrochemistry, was first discovered over 70 years ago, but recently there has been a revived interest in this field. Sonoelectrochemistry is a technology that is safe, cost-effective, environmentally friendly and energy efficient compared to other conventional methods.' The book contains chapters on the following topics, contributed from leading researchers in academia and industry:? Use of electrochemistry as a tool to investigate Cavitation Bubble Dynamics Sonoelectroanalysis Sonoelectrochemistry in environmental applications Organic Sonoelectrosynthesis Sonoelectrodeposition Influence of ultrasound on corrosion kinetics and its application to corrosion tests Sonoelectropolymerisation Sonoelectrochemical production of nanomaterials Sonochemistry and Sonoelectrochemistry in hydrogen and fuel cell technologies?

Foreword	p. xiii
About the Editor	p. xv
List of Contributors	p. xvii
Acknowledgements	p. xix
Introduction to Electrochemistry	p. 1
Introduction	p. 1
Principles of Electrochemistry	p. 1
Electron-Transfer Kinetics	p. 2
Determination of Overpotentials	p. 10
Decomposition Voltages	p. 10
Discharge Potentials	p. 10
Electroanalytical Techniques	p. 11
Voltammetry	p. 11
Amperometry	p. 17
References	p. 20
An Introduction to Sonoelectrochemistry	p. 21
Introduction to Ultrasound and Sonochemistry	p. 21
Applications of Power Ultrasound through Direct Vibrations	p. 23
Welding	p. 23
Applications of Power Ultrasound through Cavitation	p. 25
Homogeneous Reactions	p. 26
Heterogeneous Reactions Involving a Solid/Liquid Interface	p. 26
Heterogeneous Liquid/Liquid Reactions	p. 27
Electrochemistry	p. 27
Sonoelectrochemistry - The Application of Ultrasound in Electrochemistry	p. 28
Ultrasonic Factors that Influence Sonoelectrochemistry	p. 29
Examples of the Effect of Ultrasound on Electrochemical Processes under Mass Transport Conditions	p. 32
Experimental Methods for Sonoelectrochemistry	p. 34
Cell Construction	p. 34
Stability of the Electrodes Under Sonication	p. 36
Some Applications of Sonoelectrochemistry	p. 38
References	p. 40
The Use of Electrochemistry as a Tool to Investigate Cavitation Bubble Dynamics	p. 45
Introduction	p. 45
An Overview of Bubble Behaviour	p. 46
Mass Transfer Effects of Cavitation	p. 48
Isolating Single Mechanisms for Mass Transfer Enhancement	p. 48
Electrochemistry Next to a Tethered Permanent Gas Bubble	p. 51
Mass Transfer from Forced Permanent Gas Bubble Oscillation	p. 55
Mass Transfer Effects from Single Inertial Cavitation Bubbles	p. 62
Investigating Non-inertial Cavitation Under an Ultrasonic Horn	p. 65
Measuring Individual Erosion Events from Inertial Cavitation	p. 67
Conclusions	p. 73
Acknowledgements	p. 73
References	p. 73
Sonoelectroanalysis: An Overview	p. 79
Introduction	p. 79
Analysis of Pesticides	p. 87
Quantifying Nitrite	p. 87
Biogeochemistry	p. 88
Quantifying Metal in 'Life or Death' Situations	p. 89
Analysis of Trace Metals in Clinical Samples	p. 90
Biphasic Sonoelectroanalysis	p. 92
Applying Ultrasound into the Field: The Sonotrode	p. 93
Conclusions	p. 93
References	p. 94
Sonoelectrochemistry in Environmental Applications	p. 101
Introduction	p. 101
Sonoelectrochemical Degradation of Persistent Organic Pollutants	p. 102
Sonoelectrochemical Applications	p. 102
Hybrid Sonoelectrochemical Techniques Applications	p. 115
Recovery of Metals and Treatment of Toxic Inorganic Compounds	p. 121
Disinfection of Water by Hypochlorite Generation	p. 129
Soil Remediation	p. 130
Conclusions	p. 134
List of Symbols and Abbreviations	p. 134
References	p. 135
Organic Sonoelectrosynthesis	p. 141
Introduction	p. 141
Scale-Up Considerations	p. 142
Early History of Organic Sonoelectrochemistry	p. 143
Electroorganic Syntheses	p. 144
Electroreductions	p. 144
Organochalcogenides	p. 149
Synthetic Electrooxidations	p. 151
Sonoelectrochemically Produced Electrode Coatings: Desirable and Undesirable	p. 157
Other Systems	p. 161
Hydrodynamics	p. 161
Low-temperature Effects	p. 162
Conclusions	p. 163
Acknowledgements	p. 163
References	p. 163
Sonoelectrodeposition: The Use of Ultrasound in Metallic Coatings Deposition	p. 169
Introduction to Metal Plating	p. 169
Why the Need to Cover Surfaces with Metals?	p. 169
Process and Technology of Plating	p. 170
The Use of Ultrasound in Surface Treatment	p. 170
Ultrasound in the Cleaning Step for Surface Treatment Processes	p. 170
Ultrasound and Plating: Why Study Plating under Sonication?	p. 172
Electrodeposition Assisted by Ultrasound	p. 173
The Electrodeposition Process	p. 173
Ultrasonic Effects on Electrodeposited Coating Properties	p. 175
Microscopic Effects of Ultrasound on Electrodeposited Metal Coatings	p. 179
The Influence of Acoustic Energy Distribution on Coatings	p. 182
Influence of Ultrasound on Copper Electrodeposition in Unconventional Solvents	p. 187
Incorporation of Particles Assisted by Ultrasound	p. 195
Electroless Coating Assisted by Ultrasound	p. 198
The Electroless Process	p. 198
Ultrasound Effects upon Electroless Coating Properties	p. 198
Copper Coating on Non-conductive Substrates under Insonation	p. 201
References	p. 209
Influence of Ultrasound on Corrosion Kinetics and its Application to Corrosion Tests	p. 215
Introduction to Metal Corrosion	p. 215
What Exactly is Corrosion?	p. 215
Why Do Metals Corrode?	p. 215
The Price to Pay: the Economical Impact of Corrosion	p. 216
Corrosion Control Technology: the Need for Reliable Corrosion Tests	p. 217
Why Study Corrosion Under Sonication?	p. 219
Corrosion and Corrosion-Cavitation Mechanisms	p. 220
Corrosion Rate	p. 221
Electrochemical Study of Corrosion Reactions	p. 222
Forms of Corrosion	p. 223
Cavitation-Corrosion	p. 223
Influence of Ultrasound on the Corrosion Mechanisms of Metals	p. 231
Influence of Ultrasound on General Corrosion	p. 232
Influence of Ultrasound on Passivity of Metals	p. 240
Ultrasound as a Tool to Develop Accelerated Corrosion Testing	p. 242
Atmospheric Corrosion of Zinc Plated Steel	p. 242
Accelerated Corrosion Test for Stainless Steel Used in Exhaust Systems	p. 243
Accelerated Corrosion Test for Evaluating Oilfield Corrosion Inhibitors	p. 243
Accelerated Corrosion Test for Surgical Implant Materials in Body Fluids	p. 244
References	p. 244
Sonoelectropolymerisation	p. 249
Introduction to Electropolymerisation	p. 249
Innovative Processes for Electrode Activation	p. 251
Solubilisation of Monomers with Ultrasound	p. 256
Chemical Polymerisation	p. 257
Electropolymerisation under Ultrasonic Irradiation	p. 259
Effects of Ultrasound on Film Properties	p. 262
Mass-Transfer Effect	p. 262
Morphology Effect	p. 264
Doping Effect	p. 272
Effect on Local Control of Surfaces	p. 276
References	p. 278
Sonoelectrochemical Production of Nanomaterials	p. 283
Introduction	p. 283
Experimental Configurations	p. 286
Pure Metals	p. 287
Cobalt, Iron and Nickel	p. 287
Silver	p. 287
Copper	p. 288
Magnesium	p. 288
Aluminium	p. 289
Lead and Cadmium	p. 290
Core Shell Nanoparticles	p. 290
Gold	p. 292
Tungsten	p. 295
Alloy Nanoparticles	p. 295
Polymer Nanoparticles	p. 296
Conclusions	p. 296
References	p. 296
Sonochemistry and Sonoelectrochemistry in Hydrogen and Fuel Cell Technologies	p. 301
Introduction	p. 301
Sonoelectrochemical Production of Hydrogen	p. 303
Sonochemical Production of Noble Metals and Fuel Cell Electrocatalysts	p. 305
Sonochemical Mono-Metallic Syntheses	p. 306
Sonochemical Bi-Metallic Syntheses	p. 309
Sonochemical Perovskite Oxides Syntheses	p. 311
Sonoelectrochemical Production of Noble Metals and Fuel Cell Electrocatalysts	p. 311
Effect of Surfactants and Polymers	p. 315
Effect of Aqueous Solutions	p. 317
Sonochemical and Sonoelectrochemical Preparation of Fuel Cell Electrodes	p. 318
Industrial Applications of the Use of Ultrasound for the Fabrication of Fuel Cell Materials	p. 319
Conclusions	p. 320
Acknowledgement	p. 321
List of Abbreviations	p. 321
References	p. 322
Appendix: Sonochemical Effects on Electrode Kinetics	p. 327
Index	p. 335
Table of Contents provided by Ingram. All Rights Reserved.

Amazon no longer offers textbook rentals. We do!

Power Ultrasound in Electrochemistry From Versatile Laboratory Tool to Engineering Solution

Power Ultrasound in Electrochemistry From Versatile Laboratory Tool to Engineering Solution

9780470974247

0470974249

Summary

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Table of Contents

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