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Organic Chemistry
ISBN: 9780072424584 | 0072424583
Edition: 5thFormat: Hardcover
Publisher: McGraw Hill
Pub. Date: 2/1/2002
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"A Market Leading, Traditional Approach to Organic Chemistry" Throughout all seven editions, Organic Chemistry has been designed to meet the needs of the "mainstream," two-semester, undergraduate organic chemistry course. This best-selling text gives students a solid understanding of organic chemistry by stressing how fundamental reaction mechanisms function and reactions occur. With the addition of handwritten solutions, new cutting-edge molecular illustrations, updated spectroscopy coverage, seamless integration of molecular modeling exercises, and state-of-the-art multimedia tools, the 7th edition of Organic Chemistry clearly offers the most up-to-date approach to the study of organic chemistry.
| Structure Determines Properties | |
| Atoms, Electrons, and Orbitals | |
| Ionic Bonds | |
| Covalent Bonds, Lewis Structures, and the Ocelet Rule | |
| Double Bonds and Triple Bonds | |
| Polar Covalent Bonds and Electronegativity Electrostatic Potential Maps | |
| Structural Formuala of Organic Molecules | |
| Formal Charge | |
| Resonance | |
| The S... MORE | |
| Molecular Dipole Moments | |
| Curved Arrows and Chemical Reactions | |
| Acids and Bases: The Arrhenius View | |
| Acids and Bases: The Brønsted-Lowry View | |
| What Happened to pKb? | |
| How Structure Affects Acid Strength | |
| Acid-Base Equilibria | |
| Lewis Acids and Lewis Bases | |
| Summary Problems Descriptive Passage and Interpretive Problems 1: Amide Lewis Structures | |
| Alkanes and Cycloakanes: Introduction to Hydrocarbons | |
| Classes of Hydrocarbons | |
| Electron Waves and Chemical Bonds | |
| Bonding in H2: The Valence Bond Model | |
| Bonding in H2: The Molecular Orbital Model | |
| Introduction to Alkanes: Methane, Ethane, and Propane Methane and the Biosphere | |
| sp3 Hybridization and Bonding in Methane | |
| Bonding in Ethane | |
| Isomeric Alkanes: The Butanes | |
| Higher n -Alkanes | |
| The C5H12 Isomers | |
| IUPAC Nomenclature of Unbranched Alkanes What''s in a Name? Organic Nonmenclature | |
| Applying the IUPAC Rules: The Names of the C6H14 Isomers | |
| Alkyl Groups | |
| IUPAC Names of Highly Branched Alkanes | |
| Cycloalkane Nomenclature | |
| Sources of Alkanes and Cycloalkanes | |
| Physical Properties of Alkanes and Cycloalkanes | |
| Chemical Properties. Combustion of Alkanes | |
| Oxidation-Reduction in Organic Chemistry Thermochemistry | |
| sp2 Hybridization and Bonding in Ethylene | |
| sp Hybridization and Bonding in Acetylene | |
| Which Theory of Chemical Bonding is Best? | |
| Summary Problems Descriptive Passage and Interpretive Problems 2: Some Biochemical Reactions of Alkanes | |
| Alkanes andCycloalkanes: Conformations and cis-trans Stereoisomers | |
| Conformational Analysis of Ethane | |
| Conformational Analysis of Butane Molecular Mechanics Applied to Alkanes and Cycloalkanes | |
| Conformations of Higher Alkanes | |
| The Shapes of Cycloalkanes: Planar or Nonplanar | |
| Small Rings: Cyclopropane and Cyclobutane | |
| Cyclopentane | |
| Conformations of Cyclohexane | |
| Axial and Equatorial Bonds in Cyclohexane | |
| Conformational Inversion (Ring Flipping) in Cyclohexane | |
| Conformational Analysis of Monosubstituted Cyclohexanes | |
| Disubstituted Cycloalkanes. Stereoisomers Enthalpy, Free Energy, and Equilibrium Constant | |
| Conformational Analysis of Disubstituted Cyclohexanes | |
| Medium and Large Rings | |
| Polycyclic Ring Systems | |
| Heterocyclic Compounds | |
| Summary Problems Descriptive Passage and Interpretive Problems 3: Cylic Forms of Carbohydrates | |
| Alcohols and Alkyl Halides | |
| Functional Groups | |
| IUPAC Nomenclature of Alkyl Halides | |
| IUPAC Nomenclature of Alcohols | |
| Classes of Alcohols and Alkyl Halides | |
| Bonding in Alcohols and Alkyl Halides | |
| Physical Properties of Alcohols and Alkyl Halides: Intermolecular Forces | |
| Preparation of Alkyl Halides From Alcohols and Hydrogen Halides | |
| Mechanism of the Reaction of Alcohols with Hydrogen Halides | |
| Potential Energy Diagrams for Multistep Reactions. The SN1 Mechanism | |
| Structure, Bonding, and Stability of Carbocations | |
| Effect of Alcohol Structure on Reaction Rate | |
| Reaction of Primary Alcohols with Hydrogen Halides. The SN2 Mechanism | |
| Other Methods for Converting Alcohols to Alkyl Halides | |
| Halogenation of Alkanes | |
| Chlorination of Methane | |
| Structure and Stability of Free Radicals | |
| Mechanism of Methane Chlorination | |
| Halogenation of Higher Alkanes From Bond Enthalpies to Heats of Reaction | |
| Summary Problems Descriptive Passage and Interpretive Problems 4: More About Potential Energy Diagrams | |
| Structure and Preparation of Alkenes: Elimination Reactions | |
| Alkene Nomenclature | |
| Structure and Bonding in Alkenes Ethylene | |
| Isomerism in Alkenes | |
| Naming Stereoisomeric Alkenes by the E-Z Notational System | |
| Physical Properties on Alkenes | |
| Relative Stabilities of Alkenes | |
| Cycloalkenes | |
| Preparations of Alkenes: Elimination Reactions | |
| Dehydration of Alcohols | |
| Regioselectivity in Alcohol Dehydration: The Zaitsev Rule | |
| Stereoselectivity in Alcohol Dehydration | |
| The E1 and E2 Mechanisms of Alcohol Dehydration | |
| Rearrangements in Alcohol Dehydration | |
| Dehydrohalogenation of Alkyl Halides | |
| The E2 Mechanism of Dehydrohalogenation of Alkyl Halides | |
| Anti Elimination in E2 Reactions: Stereoelectronic Effects | |
| Isotope Effects and the E2 Mechanism | |
| The E1 Mechanism of Dehydrohalogenation of Alkyl Halides | |
| Summary Problems Descriptive Passage and Interpretive Problems 5: A Mechanistic Preview of Addition Reactions | |
| Reactions of Alkenes | |
| Hydrogenation of Alkenes | |
| Heats of Hydrogenation | |
| Stereochemistry of Alkene Hydrogenation | |
| Electrophilic Addition of Hydrogen Halides to Alkenes | |
| Regioselectivity of Hydrogen Halide Addition: Markovnikov''s Rule | |
| Mechanistic Basis for Markovnikov''s Rule Rules, Laws, Theories, and the Scientific Method | |
| Carbocation Rearrangements in Hydrogen Halide Addition to Alkenes | |
| Free-Radical Addition of Hydrogen Bromide to Alkenes | |
| Addition of Sulfuric Acid to Alkenes | |
| Acid-Catalyzed Hydration of Alkenes | |
| Thermodynamics of Addition - Elimination Equilibria | |
| Hydroboration-Oxidation of Alkenes | |
| Stereochemistry of Hydroboration-Oxidation | |
| Mechanism of Hydroboration-Oxidation | |
| Addition of Halogens to Alkenes | |
| Stereochemistry of Halogen Addition | |
| Mechanism of Halogen Addition to Alkenes: Halonium Ions | |
| Conversion of Alkenes to Vicinal Halohydrins | |
| Epoxidation of Alkenes | |
| Ozonolysis of Alkenes | |
| Introduction to Organic Chemical Synthesis | |
| Reactions of Alkenes with Alkenes: Polymerization Ethylene and Propane: The Most Important Industrial Organic Chemicals | |
| Summary Problems Descriptive Passage and Interpretive Problems 6: Some Unusual Electrophilic Additions | |
| Stereochemistry | |
| Molecular Chirality: Enantiomers | |
| The Chirality Center | |
| Symmetry in Achiral Structures | |
| Optical Activity | |
| Absolute and Relative Configuration | |
| The Cahn-Ingold-Prelog R-S Notation System | |
| Fischer Projections | |
| Properties of Enantiomers Chiral Drugs | |
| Reactions That Create a Chirality Center | |
| Chiral Molecules With Two Chirality Centers | |
| Achiral Molecules With Two Chirality Centers | |
| Molecules With Multiple Chirality Centers Chirality of Disubstituted Cyclohexanes | |
| Reactions That Produce Diastereomers | |
| Resolution of Enantiomers | |
| Stereoregular Polymers | |
| Chirality Centers Other Than Carbon | |
| Summary Problems Descriptive Passage and Interpretive Problems 7: Prochirality | |
| Nucleophilic Substitution | |
| Functional Group Transformation by Nucleophilic Substitution | |
| Relative Reactivity of Halide Leaving Groups | |
| The SN2 Mechanism of Nucleophilic Substitution | |
| Steric Effects and SN2 Reaction Rates | |
| Nucleophiles and Nucleophilicity | |
| The SN1 Mechanism of Nucleophilic Substitution Enzyme-Catalyzed Nucleophilic Substitution of Alkyl Halides | |
| Carbocation Stability and SN1 Reaction Rates | |
| Table of Contents provided by Publisher. All Rights Reserved. |
