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Macromolecules Containing Metal and Metal-Like Elements : Supramolecular and Self-Assembled Met...

ISBN: 9780470251447 | 0470251441
Edition: 1st
Format: Hardcover
Publisher: Wiley
Pub. Date: 11/2/2009

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SummaryTable of Contents
This book series Macromolecules Containing Metal and Metal-like Elements brings new concepts and developments in the titled area of research. Volume 9 focuses attention on the area of supramolecular chemistry, supramolecular architecture and supramolecular self-assemblies that involve materials containing metals and metal-like elements and the potential applications of these interesting hybrid materials.
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Preface
Series Preface
Supramolecular Structures and Functions with Inorganic Building Blocks
Introduction
Hybrid Lipid Thin Films
Layer-by-Layer Assemblies
Structure Transcription
Functional Mesoporous Hybrids
Future Perspectives
Acknowledgments
References
Self-Assembly of Hydrophilic Polyoxometalate Macroanions in Dilute Solutions
Introduction
Solution Behavior of POM Macroions: Soluble but Still Aggregate
Characterization of the Supramolecular Structures
Controlling the Blackberry Formation and Blackberry Size by Changing Solvent Quality
Counterion Association around Discrete POM Macroions
Counterion Condensation around Blackberries
Identification of the Driving Forces Responsible for the Blackberry Formation
Soft Nature of the Blackberries-Effect of Additional Hydrogen Bonding
Weak Electrolyte Type POMs
Effect of Additional Electrolytes
Kinetic Process of Blackberry Formation
Cation Transport over the Anionic Blackberry Membrane
Macroions in Solution: An important Linkage among Simple Ions, Polymers, Colloids, and Biosystems
Conclusions
Acknowledgments
References
Supramolecular Structures and Polyoxometalates
Introduction
Supramolecular Features of Polyoxometalate-Supported Transition-Metal Complexes
Polyoxometalate Crown Ether Complexes with Supramolecular cations
Supramolecular Water Clusters Associated with Polyoxometalates
Concluding Remarks
Acknowledgements
References
Supramolecular Coordination Networks Employing Sulfonate and Phosphonate Linkers: From Layers to Open Structures
Introduction
The Sulfonate Group as a Ligand
Layered Metal Sulfonates
Nonlayered Metal Sulfonates
Dynamic and Crystalline Metal Sulfonate Frameworks
Hydrogen Bonded Second Sphere Coordination Networks
Metal phosphonates
Conclusion
References
Transition-Metal-Based Linear Chain Compounds
Introduction
Ligand-Supported Metal Chains
Linear Chains of Chromium
Linear Metal Chains of Cobalt
Linear Chains of Copper
Linear Chains of Nickel
Linear Chains of Palladium
Unsupported Metal Chains
Linear Chain Compounds of Rhodium
Linear Chain of Iridium
The Platinum Blues
Concluding Remarks
References
Boronate-Linked Materials: Ranging from Amorphous Assemblies to Highly Structured Networks
Introduction and Scope
Supramolecular Boronate Assemblies
Traditional Hydrogen Bonded Supramolecular Assemblies
Novel Phenyl-Boron-Phenyl Sandwich Supramolecular Assembly
Coordination-Based Macrocyclic Assemblies
Coordination-Based Linear Assemblies
Covalently Linked Boronate Assemblies
Covalently Linked Macrocyclic and Cage Assemblies
Covalently Linked Linear Assemblies
Covalently Linked Network Assemblies
Summary and Outlook
References
Mixed-Metal Supramolecular Complexes Coupling Polyazine Light Absorbers and Reactive Metal Centers
Introduction
Light Absorption
Solar Water Splitting
Metal Complexes as DNA Targeting Agents
Supramolecular Charge Transfer Complexes
Cyclic Voltammetry of Charge Transfer Light Absorbers
Supramolecular Complexes Coupling Ru(II) or Os(II) Polyazine Light Absorbers and Rh(III) Reactive Metal Centers
The Complexes [(bpy)2Ru(BL)RhH2(PPh3)2]3+
Cyanide-Bridged Ru(II)-Rh(III) Complexes
Polyazine-Bridged [(bpy)2Ru(dpp)Rh(bPy)2 5+
Tridentate-Bridged Complexes: [(ttpy)Ru(tpy-(Ph)n-tpy) Rh(ttpy)]5+(n=0-2)
Ru(II)-Rh(III) Complexes Bridged with a Flexible Spacer: [(Me2phen)2Ru(Mebpy-CH2-CH2-Mebpy)Rh(Me2bpy)2]5+
Dendrimeric Ru(II)/Os(II)-Rh(III) Complexes: [M{(dpp)Rh(ppy)2}3](PF6)5
Extended Supramolecular Architectures with Fe(II)/Ru(II)/Rh(III)
Stereochemically Defined Tridentate-Bridged Ru(II)-Rh(III) Complex
Photoinitiated Electron Collection
Supramolecular Complexes Coupling Ru(II) or Os(II) Polyazine Light Absorbers to Reactive Pt(II) Metal Centers
Cyanide-Bridged Ru(II)-Pt(II) Complexes: [(bpy)2(CN)Ru(CN)Pt(dien)](ClO4)2 and [(dien)Pt(NC)(bpy)2Ru(CN)Pt(dien)](ClO4)4
A Ru(II)-Pt(II) Complex as a Chemodosimeter
Ru(II)-Pt(II) Complexes Bridged by Flexible Spacers
A bpm-Bridged Ru(II)-Pt(II) Complex: [(bpy)2Ru(bpm)PtCl2]2+
Ru(II)-Pt(II) dpp-Bridged Complexes: [(bpy)2Ru(dpp) PtMe2]2+ and [(bpy)2Ru(dpp)PtCl2]2+
Ru(II)-Pt(II) Complexes Bridged by a BL Ligand with Two Inequivalent Sites
DNA Binding of the Ru(II)-Pt(II) Complex: [(tpy)Ru(dtdeg)PtCl]Cl3
Ru(II)-Pt(II) Complexes with Amino Linkages: [(bpy)2Ru(BL)PtCl2](PF6)2 (BL = bpy(CONH (CH2)3NH2)2 and phenNHCO(COOHbpy))
Systematic Studies of Ru(II)/Os(II)-Pt(II) Complexes with Polyazine Bridging Ligands
Dendrimeric Ru(II)-Pt(II) Complexes Bridged by Polyazine Bridging Ligands
Supramolecular Complexes Coupling Ru(II) Polyazine Light Absorbers to Reactive Pd(II) Metal Centers
Ru(II)-Pd(II) Complexes Bridged by dpp and bpm Ligands: [(bpy)2Ru(dpp)PdCl2](PF6)2 and [(bpy)2Ru(bpm)PdCl2](ClO4)2
Ru(II)-Pd(II) Complexes Bridged by an Extended Polyazine Ligand: [(tBu2bpy)2Ru(tpphz)PdCl2](PF6)2
Ru(II)-Pd(II) Complexes Bridged by bpm type Ligands: [(bpy)2Ru(BL)PdMeCl]2+
A Ru(II)-Pd(II) Complex Bridged by a Flexible Polyazine Bridging Ligand: [(bpy)2Ru(DMB)PdCl2]2+
Conclusions
Acknowledgments
References
Supramolecular Hybrid Materials-Integrating Functionality with Sensing (Ramón Martínez-Máñez, Félix Sanceno´n, Ana Belén Descalzo
Introduction
Enhanced Coordination by Preorganization. Surface Chelate Effect and Signaling
Enhanced Signaling by Preorganization
Assembly-Disassembly
Selectivity by Polarity and Size. Biomimetic Signaling
Switching, Gating and Signaling
Conclusions
Acknowledgments
References
Molecular Recognition Process between Nucleobases and Metal-Oxalato Frameworks
Introduction
Molecular Recognition
Nucleobases
Oxalate
Metal-Oxalato-Nucleobase Extended Systems
Other metal-nucleobase 1D Extended Systems
Hybrid Systems Based on Metal-Oxalato and Protonated Nucleobases
Conclusions
References
Crystal Engineering of Coordination Polymers
Introduction
Synthetic Approaches
The Node-and-Spacer Paradigm
Flexible Ligand Approach: Polycarboxylates as Anionic Linkers. A Case Study-Malonato Complexes
The Building-Block Approach
Conclusions and Perspectives
Acknowledgments
References
Index
Table of Contents provided by Publisher. All Rights Reserved.


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