Macromolecules Containing Metal and Metal-Like Elements, Photophysics and Photochemistry of Met...
ISBN: 9780470597743 | 0470597747
Edition: 1stFormat: Hardcover
Publisher: Wiley
Pub. Date: 5/24/2010
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Metal- and metalloid-containing macromolecules are defined as large molecules (i.e., polymers, DNA, proteins) that contain a metal or metalloid group affiliated with the molecule. This volume describes what is possible with metal-containing polymers where the metal is an essential ingredient in obtaining desired optical and electronic properties. Covering applications in nonlinear optical materials, solar cells, light-emitting diodes, photovoltaic cells, field-effect transistors, chemosensing devices, and biosensing devices, this indispensible ... MORE
| Preface | |
| Series Preface | |
| Introduction to Photophysics and Photochemistry | |
| General | |
| Photophysics and Photochemistry | |
| Light Absorption | |
| Luminescence | |
| Emission Lifetime | |
| Ground and Excited State Molecular Interactions | |
| Energy and Electron Transfer Excited State Interactions Reactions | |
| En... MORE | |
| Electron Transfer | |
| Nonlinear Optical Behavior | |
| Photoconductive and Photonic Polymers | |
| Photosynthesis | |
| Purple Photosynthetic Bacteria | |
| Green Sulfur Bacteria | |
| Organometallic Polymers and Synthetic Photosynthesis Systems | |
| Summary | |
| References Additional Readings | |
| References | |
| Luminescent Organometallic Coordination Polymers Built on Isocyanide Bridging Ligands | |
| Introduction | |
| Luminescent Organometallic Polynuclear Systems and Coordination Polymers Containing a Terminal Isocyanide Ligand | |
| Luminescent Polymeric Systems Containing an Isocyanide Ligand Assembled via M...M Interactions | |
| Luminescent Organometallic Polymetallic Systems and Coordination Polymers Containing Bridging Isocyanides | |
| Conclusion | |
| Acknowledgments | |
| References | |
| Luminescent Oligomeric and Polymeric Copper Coordination Compounds Assembled by Thioether Ligands | |
| Introduction | |
| Background Informations | |
| Luminescent Copper Polymers Assembled by Thioether Ligands | |
| Copper Polymers Assembled by Monothioether Ligands RSR | |
| Copper Polymers Assembled by Aromatic Dithioether Ligands | |
| Copper Polymers Assembled by Aliphatic Dithioether and Polythioether Ligands | |
| Copper Polymers Assembled by Dithioether and Polythioether Ligands Bearing Heteroelements in the Spacer Unit | |
| Conclusion | |
| Acknowledgments | |
| References | |
| Applications of Metal Containing Polymers in Organic Solar Cells | |
| Introduction | |
| Types of Organic Solar Cells | |
| Dye-Sensitized Solar Cells | |
| Organic Thin Film Solar cells | |
| Solar Cell Characterizations | |
| Metal Containing Polymers in Solar Cells | |
| Dye-Sensitized Solar Cells | |
| Organic Thin Film Solar Cells | |
| Summary | |
| Acknowledgments | |
| References | |
| Functional Silole-Containing Polymers | |
| Introduction | |
| Electronic Transition and Band Gap | |
| Light Emission | |
| Photoluminescence | |
| Electroluminescence | |
| Bulk-Heterojuction Photovoltaic Cells | |
| Field Effect Transistors | |
| Aggregation-Induced Emission | |
| Chemosensors | |
| Conductivity | |
| Optical Limiting | |
| Summary | |
| Acknowledgments | |
| References | |
| Photophysics and Photochemistry of Polysilanes for Electronic Applications | |
| Introduction | |
| Synthesis of Electronic-Grade Polysilanes | |
| Band Structure | |
| Photophysics | |
| Influence of the Backbone Structure | |
| Side Groups | |
| Nanostructured Polysilanes | |
| PL Quenching by Doping | |
| Energy Transfer | |
| Electroluminescence | |
| Cathodoluminescence | |
| Interaction with Photoelectrons | |
| Photochemistry | |
| Photo-Oxidation | |
| Polysilane Thin Films for Electronic Devices | |
| LED | |
| Photoconductors | |
| Photovoltaics | |
| Lithography | |
| Electron Beam | |
| Polysilane Films for Optical Devices | |
| NLO | |
| Summary | |
| References | |
| Polymers with Metal-Metal Bonds as Models in Mechanistic Studies of Polymer Photodegradation | |
| Introduction | |
| Experimental Strategies | |
| Synthesis of Polymers with Metal-Metal Bonds along their Backbones | |
| Step-Growth Polymers | |
| ADMET Polymerization | |
| Chain-Growth Polymers | |
| Photochemical Reactions of the Polymers in Solution | |
| Photochemistry in the Solid State | |
| Factors Controlling the Rate of Polymer Photochemical Degradation in the Solid State | |
| Temperature Effects | |
| Interpreting the Kinetics of Polymer Degradation in the Solid State | |
| Photodegradation Rate Dependence on Polymer Curing Time | |
| The Effects of Stress on Polymer Degradation | |
| Kinetics of Polymer Formation | |
| Concluding Remarks on the Importance of Radical-Radical Recombination on the Efficiency of Polymer Photochemical Degradation | |
| Acknowledgments | |
| References | |
| Optical Properties and Photophysics of Platinum-Containing Poly (aryleneethynylene) | |
| Introduction | |
| Synthetic Methods and Materials Characterization | |
| Optical and Photophysical Properties | |
| Energy Gap Law for Triplet States | |
| Phosphorescence Color Tuning of Metallopolyynes | |
| Roles of Metallopolyynes in Optoelectronic and Photonic Devices | |
| Summary | |
| Acknowledgments | |
| References | |
| Luminescence in Polymetallic Gold-Heteronuclear Derivatives | |
| Introduction and Background | |
| Luminescent Gold-Silver Derivatives | |
| Supramolecular Gold-Silver Complexes with Bidentate Ligands | |
| Supramolecular Gold-Silver Complexes with Tridentate Ligands | |
| Supramolecular Gold-Silver Complexes Built with Metallic Cationic and Anionic Counterparts | |
| Luminescent Gold-Copper Derivatives | |
| Luminescent Gold-Thallium Derivatives | |
| Supramolecular Gold-Thallium Complexes with Bidentate Ligands | |
| Supramolecular Gold-Thallium Complexes through Acid-Base Reactions | |
| Luminescent Gold-Lead Derivatives | |
| Luminescent Gold-Platinum Derivatives | |
| Luminescent Gold-Mercury Derivatives | |
| Conclusion | |
| References | |
| Functional Self-Assembled Zinc(II) Coordination Polymers | |
| Introduction | |
| Zinc(II) Terpyridine Polymers | |
| Zinc(II) Schiff Base Polymer | |
| Summary | |
| Acknowledgment | |
| References | |
| Redox and Photo Functions of Metal Complex Oligomer and Polymer Wires on the Electrode | |
| Introduction | |
| Bottom-Up Fabrication of Redox-Conducting Metal Complex Oligomers on an Electrode Surface and Their Redox Conduction Behavior | |
| Bottom-Up Fabrication of Metal Complex Oligomer and Polymer Wires | |
| Electron Transport Behavior of the Molecular Wires on the Electrode | |
| Photoelectric Conversion System Using Porphyrin and Redox-Conducting Metal Complex Wires | |
| Bottom-Up Fabrication of the Porphyrin-Terminated Redox-Conducting Metal Complex Film on ITO | |
| Photoelectrochemical Properties of the Porphyrin-Terminated Redox-Conducting Metal Complex Film on ITO | |
| Biophotosensor and Biophotoelectrode Composed of Cyanobacterial Photosystem I and Molecular Wires | |
| Biophotosensor Composed of Cyanobacterial Photosystem I, Molecular Wire, Gold Nanoparticle, and Transistor | |
| Biophotoelectrode Composed of Cyanobacterial Photosystem I and Molecular Wires | |
| Conclusion | |
| References | |
| Index | |
| Table of Contents provided by Publisher. All Rights Reserved. |
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